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Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2

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Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2

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Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2 supplier Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2 supplier

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Place of Origin: Weifang,China
Brand Name: RuzE
Model Number: TC-9041

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Price: Negotiable
Packaging Details: 25kg
Delivery Time: 5-10work days
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Detailed Product Description
Product Name: Magnesium Bromide Synonyms: Hydrobromic Acid Magnesium Salt;Magnesium Bromide (MgBr2);magnesiumbromide(mgbr2);MgBr2;MAGNESIUM BROMIDE, ANHYDROUS, POWDER, 99 .995%;MAGNESIUM BROMIDE ANHYDROUS 98%;NCI-H661 Cell;MagnesiuM BroMide, 98%, Pure, Anhydrous
CAS: 7789-48-2 MF: Br2Mg
MW: 184.11 EINECS: 232-170-9

Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2

 

                                           Magnesium Bromide Hexahydrate Cas No.7789-48-2

 

[Product Name]:Magnesium Bromide Hexahydrate

[Molecular Formula]: MgBr2

[Molecular Weight] : 184.11

[Cas No]:7789-48-2

[Color]:white

[Appearance]: Fine powder

 

Test items Unit Index Result
Exterior   White crystalline White crystalline
Content % ≥98.0 98.23
PH value(5%)   5.0-7.5 6085
CL- % ≤0.6 0.19
SO42- % ≤0.05 <0.05
BrO3-   No response No response
Pb % ≤0.001 0.0005
 

Magnesium bromide Chemical Properties

Melting point 711 °C(lit.)
Boiling point 1248.47°C (estimate)
density 3.72 g/mL at 25 °C(lit.)
form Powder
color off-white
Specific Gravity 3.72
Water Solubility g/100g H2O: 100.6 (25°C), 125.4 (100°C); solid phase, MgBr2 ·6H2O [KRU93]
Merck 13,5681
Stability: hygroscopic
CAS DataBase Reference 7789-48-2(CAS DataBase Reference)
NIST Chemistry Reference Magnesium dibromide(7789-48-2)
EPA Substance Registry System Magnesium bromide (MgBr2)(7789-48-2)

Safety Information

Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 1
HS Code 28275900

Magnesium bromide Usage And Synthesis

Occurrence and Uses Magnesium bromide occurs in sea water, surface and subterranean brines, and salt deposits. It is an electrolyte component in certain dry cells. In medicine, it is a sedative and anticonvulsant for treatment of nervous disorder. It also is used in organic synthesis forming several addition compounds.
Physical Properties The anhydrous MgBr2 is a white crystalline substance; hexagonal crystals; deliquescent; density 3.72 g/cm3; melts at 700°C; highly soluble in water (101.5g/100mL at 20°C); moderately soluble in methanol and ethanol (21.8 and 6.9 g/mL at 20°C, respectively).
The hexahydrate, MgBr2•6H2O consists of colorless monoclinic crystals; bitter taste; hygroscopic; fluoresce in x-rays; density 2.07 g/cm3; melts at 172.4°C; intensely soluble in water, 316 g/100 mL at 0°C; dissolves in methanol and ethanol; slightly soluble in ammonia solution.
Preparation Magnesium bromide is prepared by treating magnesium oxide with hydrobromic acid and subsequent crystallization above 0°C. The product is hexahydrate, MgBr2•6H2O:
MgO + 2HBr → MgBr2 + H2O
The anhydrous MgBr2 may be obtained by heating the hexahydrate with dry hydrogen bromide gas. Magnesium bromide also can be made from its elements. Heating magnesium metal with bromine vapor yields the salt:
Mg + Br2 → MgBr2
Magnesium bromide, like the chloride salt, is obtained from sea water (see Magnesium and Magnesium chloride). In this process, magnesium hydroxide precipitated from sea water is neutralized with hydrobromic acid, and MgBr2 is obtained by crystallization.
Chemical Properties Colorless, very deliquescent crystals; bitter taste. Soluble in water; slightly soluble in alcohol.
Uses Organic syntheses, medicine (sedative).
Uses The major use of MgBr2 has been in the commercial production of bromine. The Dow process is an electrolytic method of bromine extraction from brine, and was Herbert Dow’s second revolutionary process for generating bromine commercially (1889).
Magnesium bromide has also been used in organic syntheses. An efficient and environmentally friendly procedure for the one-pot synthesis of tetrahydropyrimidines from aldehydes, a-diketones and urea/thiourea by using magnesium bromide as an inexpensive and easily available catalyst under solvent-free conditions has been described. Compared with the classical Biginelli reaction conditions, this new method has the advantage of good to excellent yields (74%–94%) and short reaction times (45–90 min). The structure of the Biginelli reaction product from a-diketone, salicylaldehyde and urea has been proposed to possess an oxygen bridge by cyclization (intramolecular Michael addition).
Preparation Magnesium bromide is prepared by treating MgO with hydrobromic acid and then crystallization above 0.0°C in solution. The product is the hexahydrate salt:
MgO+2HBr→MgBr2+H2O→MgBr2·6H2O
The anhydrous form may also be prepared by heating the hexah
Purification Methods Crystallise it from EtOH or H2O (3.3g/mL). Dry it in a vacuum at ~150o, or heat the hydrate in a stream of HCl. It is very deliquescent. [Ehrlich in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 909 1963.]

Magnesium bromide Preparation Products And Raw materials

Preparation Products Bromine-->DIMETHYL METHOXYMALONATE
Raw materials Bromine-->Dimethoate-->Magnesium hydroxide

Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2

Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2

 

Fine Powder Inorganic Bromide Magnesium Bromide Hexahydrate CAS 7789-48-2

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